Note: You must be an organization member to see people's roles in your organization.
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In the top right corner of GitHub Enterprise Server, click your profile photo, then click Your profile.  
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On the left side of your profile page, under "Organizations", click the icon for your organization.  
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Under your organization name, click People.  
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You will see a list of the people in your organization. To filter the list by role, click Role and select the role you're searching for. 